6533b82dfe1ef96bd12907da

RESEARCH PRODUCT

Combination of Confocal Raman Spectroscopy and Electron Microscopy on the Same Individual Bundles of Single-Walled Carbon Nanotubes

Alf MewsJixue LiJialong ZhaoChaoyang JiangUte Kolb

subject

Materials sciencebusiness.industryMechanical EngineeringConfocalAnalytical chemistryBioengineeringGeneral ChemistryCarbon nanotubeCondensed Matter Physicslaw.inventionOptical properties of carbon nanotubesCondensed Matter::Materials Sciencesymbols.namesakeCarbon filmTransmission electron microscopylawMicroscopysymbolsOptoelectronicsGeneral Materials ScienceElectron microscopebusinessRaman spectroscopy

description

We report a method to investigate the same individual single-walled carbon nanotube (SWNT) bundles with both transmission electron microscopy (TEM) and Raman spectroscopy. Free-standing individual bundles are obtained by depositing a solution of suspend SWNTs on a carbon film with a regular pattern of holes, which can be localized by TEM and also by confocal Raman microscopy. While most of the TEM images predict that the bundles consist of tubes with a similar diameter, we will show that occasionally a certain tube diameter can be associated with a particular radial breathing mode frequency of the Raman spectrum. Single-walled carbon nanotubes (SWNTs) are one-dimensional molecular structures with diameters in the range of a few nanometers. The outstanding mechanical and electrical properties of these materials have generated significant

https://doi.org/10.1021/nl025738o