6533b82dfe1ef96bd12911b6
RESEARCH PRODUCT
Polymerization of methyl and phenyl oxazoline initiated with alkyl chloroformates
Rolf C. SchulzAndrzej Dworaksubject
chemistry.chemical_classificationtechnology industry and agricultureChain transfermacromolecular substancesGeneral ChemistryOxazolinePhotochemistryLiving free-radical polymerizationchemistry.chemical_compoundChain-growth polymerizationchemistryPolymerizationPolymer chemistryReversible addition−fragmentation chain-transfer polymerizationIonic polymerizationAlkyldescription
It has been shown that alkyl chloroformates are capable of initiating the polymerization of oxazolines. Esters itself initiate rather slowly and the polymerization proceeds via covalent growing species. Exchange of counter ions with triflate or iodide anions leads to faster initiation and higher reaction rates. The polymerization is of living character.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-09-01 | Bulletin des Sociétés Chimiques Belges |