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RESEARCH PRODUCT
Gluten-free flours from cereals, pseudocereals and legumes: Phenolic fingerprints and in vitro antioxidant properties.
Gabriele RocchettiGianluca GiubertiJose Manuel Lorenzo RodriguezLuigi LuciniFrancisco J. Barbasubject
AntioxidantGlutensBlack ricemedicine.medical_treatmentFlour01 natural sciencesFlavonesCatechin (PubChem CID: 9064)AntioxidantsAnalytical ChemistryAnthocyaninschemistry.chemical_compound5-Pentadecylresorcinol (PubChem CID: 76617)Sesamin (PubChem CID: 72307)0404 agricultural biotechnologyFlavonolsPhenolsSettore AGR/13 - CHIMICA AGRARIAmedicineFood science5-Pentadecylresorcinol (PubChem CID: 76617); Anthocyanins; Antioxidants; Catechin (PubChem CID: 9064); Cyanidin 3-O-glucoside (PubChem CID: 12303203); Ferulic acid (PubChem CID: 445858); Food metabolomics; Legumes; Matairesinol (PubChem CID: 119205); Polyphenols; Pseudo-cereals; Sesamin (PubChem CID: 72307); Tyrosol (PubChem CID: 10393); Analytical Chemistry; Food Sciencechemistry.chemical_classificationChemistry010401 analytical chemistryFood metabolomicsPolyphenolsTyrosol (PubChem CID: 10393)Fabaceae04 agricultural and veterinary sciencesGeneral MedicineLegumes040401 food scienceGluten0104 chemical sciencesPseudo-cerealsTyrosolSettore AGR/15 - SCIENZE E TECNOLOGIE ALIMENTARIPolyphenolMatairesinol (PubChem CID: 119205)Gluten freeEdible GrainFerulic acid (PubChem CID: 445858)Cyanidin 3-O-glucoside (PubChem CID: 12303203)Food Sciencedescription
The interest in gluten-free (GF) products increases together with the increase in gluten-sensitive people. However, GF foods might have decreased nutritional quality as compared to the gluten containing counterparts. In this work, an investigation of the phenolic and antioxidant profile in 18 GF flours belonging to legumes, cereals and pseudocereals was achieved. Significant differences could be observed across samples. Total phenolic content was highest in violet rice flours, whereas total anthocyanins were highest in violet, nerone, and black rice flours. FRAP and ORAC antioxidant activities were correlated to phenolic contents and found to be higher in violet rice flours. Metabolomics highlighted a wide diversity in phenolics, with flavonoids (197 compounds ascribable to anthocyanins, flavones, flavanones, isoflavonoids, flavonols, and flavanols), phenolic acids (74 compounds belonging to hydroxycinnamics, hydroxybenzoics, and hydroxyphenylacetics), and tyrosol derivatives the most represented. Finally, OPLS-DA multivariate statistics outlined flavonoids, furofurans and phenolic acids as the most discriminant phenolics.
year | journal | country | edition | language |
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2018-02-26 | Food chemistry |