6533b82dfe1ef96bd12914f3

RESEARCH PRODUCT

Improvement of partition coefficients determination of aroma compounds in food matrices by the phase ratio variation method

Elisabeth GuichardIsabelle AndriotAnne TromelinSamuel Lubbers

subject

phase ratio variation (PRv)[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionAnalytical chemistryIngénierie des alimentspartition coefficient01 natural sciencesaroma retention-release0404 agricultural biotechnology[SDV.IDA]Life Sciences [q-bio]/Food engineeringFood and NutritionFood engineeringAromaComputingMilieux_MISCELLANEOUSbiologyChemistry010401 analytical chemistry[ SDV.IDA ] Life Sciences [q-bio]/Food engineering04 agricultural and veterinary sciencesbiology.organism_classification040401 food science0104 chemical sciencesPartition coefficient[SDV.AEN] Life Sciences [q-bio]/Food and Nutritionphase ratio variation (PRv);partition coefficient;liquid vapor equilibrium;aroma retention-releasePhase ratioAlimentation et Nutritionliquid vapor equilibriumComputingMethodologies_GENERAL[SDV.AEN]Life Sciences [q-bio]/Food and Nutrition

description

The Phase Ratio Variation (PRV) method is a very valuable method commonly used for liquid/vapor partition coefficients data acquisition of aroma compounds. Nevertheless, some limits are linked to this method, especially for volatile compounds. A careful examination of the PRV equation leads us to propose the following expression: 1/Cvap-real =(nliq/n0) x 1/Cvap-ideal = (nliq/n0) x (1/KC0 + (1/Co) b), We performed an examination for two cases of K values (K1=0.001 and K2=0.05), putting forward that a carefully choice of b range values is crucial for reliability of the regression calculation 1/A versus b.

https://hal-univ-bourgogne.archives-ouvertes.fr/hal-00722922