6533b82dfe1ef96bd1291b89

RESEARCH PRODUCT

Synthesis and characterization of [Fe(III)(qsal)2][M(III)(pds)2] (M=Cu, Au)

J.c. DiasA. Soriano-portilloM. Clemente-léonC. Giménez-saizJ.r. Galán-mascarósC.j. Gómez-garcı´aE. Coronado

subject

Inorganic ChemistryDiffractionCrystallographyMagnetic measurementsChemistrySpin crossoverMaterials ChemistrySpin transitionPhysical and Theoretical ChemistrySingle crystalCharacterization (materials science)

description

Abstract Salts of the Fe(III) spin crossover cation [FeIII(qsal)2]+ (qsalH = N-(8-quinolyl)salicylaldimine) and monoanions [MIII(pds)2]− (M = Cu, Au; pds = pirazine-2,3-diselenolate) with formula [FeIII(qsal)2][MIII(pds)2] were prepared and characterized by single crystal X-ray diffraction and magnetic measurements. These two salts present magnetic properties essentially due to the FeIII centres in the high-spin state (S = 5/2), and do not have any spin transition.

yearjournalcountryeditionlanguage
2007-10-01Inorganica Chimica Acta
https://doi.org/10.1016/j.ica.2007.02.004