6533b82dfe1ef96bd1291c01

RESEARCH PRODUCT

Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system

José Martínez-lilloNicolás MolinerCarlos Rojas-dottiAdrián Sanchis-perucho

subject

Materials scienceCondensed matter physicsField (physics)010405 organic chemistry010402 general chemistry01 natural sciencesOxalate0104 chemical sciencesInorganic ChemistryMetalMagnetizationchemistry.chemical_compoundchemistryTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYvisual_artvisual_art.visual_art_mediumRelaxation (physics)

description

The compound (NBu4)4[ZnII{ReIVCl4(μ-ox)}3] (1) [NBu4+ = tetra-n-butylammonium cation and ox2− = oxalate dianion] is the first example of an oxalato-bridged ZnII system coordinated to a 5d metal ion that exhibits slow relaxation of magnetisation.

https://doi.org/10.1039/c8dt03728k