6533b82dfe1ef96bd1291c0e
RESEARCH PRODUCT
Synthesis And Sorptive Properties Of Dodecasil 1 H With An Acessible Pore System
M.d. GrebnerK.k. UngerFerdi SchüthFerdi SchüthH. Reichertsubject
CrystallographyTemplate freeAdsorptionMorphology (linguistics)Materials scienceChemical engineeringNucleationPore systemParticle sizeSeed crystaldescription
Abstract The synthesis of Dodecasil 1H was studied in the system SiO2/1-adamantylamine/NH3/water with the objective of controlling the particle size and the morphology of the crystals. Since nucleation occurs in a very early stage of the synthesis, the heating rate to the final temperature have a strong influence on both parameters. Using seed crystals and such a heating programme, the expensive template 1-adamantylamine can be reduced to so small amounts, that a nearly template free pore system is achieved. The emptiness of the pore system was demonstrated from adsorption measurement using He and H2.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1994-01-01 |