6533b82dfe1ef96bd1291cf7
RESEARCH PRODUCT
Unprecedented intramolecular pancake bonding in a {Dy2} single-molecule magnet
Niki MavraganiMaykon Alves LemesPaul RichardsonBulat GabidullinMuralee MurugesuYixin ZhangJani O. MoilanenJaclyn L. Brussosubject
Dc fieldMaterials science010405 organic chemistry010402 general chemistry01 natural sciences0104 chemical sciences3. Good healthInorganic ChemistryMetalCrystallographyIntramolecular forceMagnetvisual_artvisual_art.visual_art_mediumSingle-molecule magnetdescription
The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands, affording [MIII2(μ-(bpytz)2)(THMD)4](M = Dy, Y; bpytz = 3,6-bis(3,5-dimethyl-pyrazolyl)-1,2,4,5-tetrazine; TMHD = 2,2,6,6-tetramethyl-3,5-heptanedionate). To provide a cohesive magneto-structural correlation, the mono bis(pyrazolyl)-tetrazine bridged congener [DyIII2(μ-bpytz)(THMD)6]·4(C6H6) was also isolated. Both metal complexes exhibit single-molecule magnet behaviour under an applied dc field.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-01 | Inorganic Chemistry Frontiers |