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RESEARCH PRODUCT
Catalytic Synergism in a C60IL10TEMPO2 Hybrid in the Efficient Oxidation of Alcohols
Francesco GiacaloneVincenzo CampiscianoMichelangelo GruttadauriaHazi Ahmad Beejapursubject
FullereneChemistryalcoholoxidationRadicalfullereneGeneral ChemistrySettore CHIM/06 - Chimica OrganicaCombinatorial chemistryCatalysischemistry.chemical_compoundAdsorptionBromidePhase (matter)Alcohol oxidationOrganic chemistry2266-tetramethylpiperidine 1-oxyl (TEMPO)ionic liquiddescription
A novel fullerene (5:1)hexakisadduct bearing two 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) radicals and ten 1-propyl-3-methylimida- zolium bromide moieties has been synthesized and characterized. Such an C60IL10TEMPO2 hybrid has been successfully employed as a catalyst in the se- lective oxidation of a wide series of alcohols and is highly active at just 0.1 mol% loading. Moreover, it can be easily recovered by adsorption onto a multi- layered covalently-linked SILP phase (mlc-SILP) through a "release and catch" approach and reused for up to 12 cycles without loss in efficiency. Inter- estingly, a catalytic synergistic effect of TEMPO and imidazolium bromide moieties combined in the same hybrid has been clearly shown.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-12-08 |