6533b82efe1ef96bd12925c3
RESEARCH PRODUCT
Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds
Elina KaleniusKari RissanenShilin YuAntonio Fronterasubject
010405 organic chemistryLigandMetals and Alloyschemistry.chemical_elementGeneral Chemistry010402 general chemistryElectrostaticsIodine01 natural sciencesCatalysis0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonGas phasechemistry.chemical_compoundchemistryHexafluorophosphatePolymer chemistryHalogenMaterials ChemistryCeramics and CompositesAnion bindingdescription
New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-01-01 | Chemical Communications |