ChemInform Abstract: Remarkable Effect of Lithium Bromide in the Enantioselective Protonation with α-Sulfinyl Alcohols.

6533b82efe1ef96bd1292609

RESEARCH PRODUCT

ChemInform Abstract: Remarkable Effect of Lithium Bromide in the Enantioselective Protonation with α-Sulfinyl Alcohols.

Pedro Aleman Luis R. Domingo Mercedes Medio-simón Gregorio Asensio

subject

chemistry.chemical_compound chemistry Lithium bromide Enantioselective synthesis Tetralone Protonation General Medicine Medicinal chemistry

description

Abstract The favourable effect of lithium bromide enhancing the facial enantioselectivity in the protonation of methyl tetralone enolate with α-sulfinyl alcohols is described. Theoretical calculations allow to propose a model to explain the stereochemical course of the protonation reaction.

year	journal	country	edition	language
2010-06-20	ChemInform

https://doi.org/10.1002/chin.199831087

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