6533b82efe1ef96bd1292643

RESEARCH PRODUCT

Spectrophotometric analysis of mixtures of two components with extensively or completely overlapping spectra by the H-point standard additions method

Ana Molina BenetFrancisco Bosch ReigPilar Campíns Falcó

subject

Resolution (mass spectrometry)ChemistryStandard additionAnalytical chemistryBinary numberPoint (geometry)Absorption (chemistry)Mass spectrometryBiochemistrySpectral lineAnalytical Chemistry

description

This paper discusses the requirements and scope of application of the H-Point Standard Additions Method (HPSAM) for resolving binary mixtures. Various mixtures of dyes with extensively or completely overlapping spectra were assayed with accurate, precise results. The method thus developed was also applied to the spectrophotometric resolution of binary mixtures of phenol and o-cresol, the absorption bands of which lie in similar positions and feature similar absorptivities.

https://doi.org/10.1007/bf00322777