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RESEARCH PRODUCT
Crystal structure and magnetic properties of Cu(TIM)CuBr4: An alternating site-alternating exchange chain system
Carlos J. Gómez-garcíaRoger D. Willettsubject
Chain structureCrystallographyNuclear magnetic resonanceMaterials scienceChain (algebraic topology)Atomic force microscopyLigandChain systemCrystal structureCondensed Matter PhysicsElectronic Optical and Magnetic Materialsdescription
Abstract The title compound, Cu(TIM)CuBr4 (where TIM is a macrocycle ligand) is a member of the Cu(TIM)MX4 family, which contains linear chain structures with ⋯ Cu ⋯ X – M – X ⋯ Cu ⋯ X – M - ⋯ linkages. This chain structure defines an alternating exchange/alternating site 1d system. For M=Cu, alternating FM/AFM chains are formed with JFM>| JAFM|. Structural and magnetic data are presented, along with an analysis of the exchange pathways.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-09-01 | Journal of Magnetism and Magnetic Materials |