6533b82efe1ef96bd1292938

RESEARCH PRODUCT

Reduction of tris(benzene-1,2-dithiolate)molybdenum(VI) by hydroxide ions in dry tetrahydrofuran solution.

Elisa LlopisAntonio CervillaFrancisco Pérez-pla

subject

UNESCO::QUÍMICAInorganic chemistrychemistry.chemical_element:QUÍMICA [UNESCO]CatalysisReaction ratechemistry.chemical_compoundMaterials ChemistryReduction ; Hydroxide ions ; Tetrahydrofuran solution ; Hydrogen peroxide ; OH2Hydrogen peroxideBenzeneTetrahydrofuranReductionUNESCO::QUÍMICA::Química inorgánicaTetrabutylammonium hydroxideMetals and AlloysGeneral ChemistryHydrogen peroxide:QUÍMICA::Química inorgánica [UNESCO]Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsHydroxide ionschemistryOH2MolybdenumYield (chemistry)Ceramics and CompositesHydroxideTetrahydrofuran solution

description

Tris(benzene-1,2-dithiolate)molybdenum(VI) reacts rapidly and quantitatively with tetrabutylammonium hydroxide to yield the corresponding Mo(V) and Mo(IV) complexes and hydrogen peroxide; the reaction has been executed in dry tetrahydrofuran where the reaction rate shows a fair dependence on complex and OH2 concentrations. Cervilla Avalos, Antonio, Antonio.Cervilla@uv.es ; Perez Pla, Francisco, Francisco.Perez@uv.es ; Llopis Jover, Elisa, Elisa.Llopis@uv.es

yearjournalcountryeditionlanguage
2001-01-01Chemical communications (Cambridge, England)
10.1039/b106123mhttps://pubmed.ncbi.nlm.nih.gov/12240061