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RESEARCH PRODUCT
Antimony-121 mössbauer and infrared spectral study on halophenylantimonate(III) Compounds
F. Di BiancaGiuseppe AlonzoTerence C. GibbNuccio Bertazzisubject
InfraredOrganic ChemistryAnalytical chemistryInfrared spectroscopychemistry.chemical_elementElectronBiochemistryInorganic ChemistryAntimonychemistryMössbauer spectroscopyMaterials ChemistryPhysical chemistryPhysical and Theoretical ChemistrySpectral dataLone pairElectric field gradientdescription
Abstract The synthesis and the 121 Sb Mossbauer and infrared spectra of halophenylantimonates(III) M[PhSbX 3 ] (M Me 4 N, Ph 4 As;X Cl, Br, I) are reported, and the spectral data are discussed and compared with those of SbX 4 and other related systems. The results are in accord with the participation of the antimony 5s electrons in the SbPh bond. In the interpretation of the electric field gradient, the contributions to V zz from both the lone pair and the SbPh bond electron densities are assumed to be dominant.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1981-04-01 | Journal of Organometallic Chemistry |