6533b82efe1ef96bd1293097

RESEARCH PRODUCT

29SiH4 and 30SiH4: Dipole moment parameters of the dyad from Stark effect observations with laser sidebands

Michel LoeteW.a. KreinerH. PrinzJean-marie Jouvard

subject

PhysicsSidebandbusiness.industryInfraredLaserAtomic and Molecular Physics and Opticslaw.inventionsymbols.namesakeDipoleOpticsStark effectlawMoment (physics)Physics::Atomic and Molecular ClusterssymbolsPhysics::Atomic PhysicsPhysics::Chemical PhysicsPhysical and Theoretical ChemistryAtomic physicsbusinessSpectroscopyTunable laserMicrowave

description

Abstract The linear Stark effect within the ν 2 ν 4 dyad of 29SiH4 and 30SiH4 has been investigated by applying the infrared sideband technique at microwave modulation frequencies. Two vibration-induced dipole moment parameters have been measured for each isotopomer on natural abundance samples.

https://doi.org/10.1016/0022-2852(90)90240-q