6533b82efe1ef96bd129314d
RESEARCH PRODUCT
Dithiametacyclophane mit Dreifachbindungen
Herbert MeierHeinz KolshornYujia Daisubject
Inorganic ChemistryMolecular dynamicschemistry.chemical_compoundThioureaChemistryHalogenTriple bondm-XylenePhotochemistryMedicinal chemistryCyclophanedescription
Dithiametacyclophanes with Triple Bonds Schemes 1 and 2 show the syntheses of dithia[8]metacyclo-phanes 4a-d and tetrathia[m.n]metacyclophanes 9, 10 by cyclization reactions applying the cesium effect. All these cyclophanes contain C—C triple bonds which influence the molecular dynamics; especially the halogen substituents in 4b-d obstruct the topomerization.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1994-08-01 | Chemische Berichte |