6533b82efe1ef96bd1293263

RESEARCH PRODUCT

Photoluminescent Cu(i) vs. Ag(i) complexes: slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states.

Rubén D. CostaJosé M. Carbonell-vilarMarta Viciano-chumillasDonatella ArmentanoJoan CanoElisa FrestaElisa Fresta

subject

PhotoluminescenceMaterials science010405 organic chemistryXantphoschemistry.chemical_element010402 general chemistry01 natural sciencesCopper0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryExcited state

description

This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4'-(MeO)2-2,2'-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9'-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.

yearjournalcountryeditionlanguage
2019-04-24Dalton transactions (Cambridge, England : 2003)
10.1039/c9dt00772ehttps://pubmed.ncbi.nlm.nih.gov/31011739