On the mechanistic behavior of highly efficient palladium-tetraphosphine catalytic systems for cross-coupling reactions: first spectroscopic and electrochemical studies of oxidative addition on Pd(0)/multidentate ferrocenylpolyphosphine complexes

6533b82ffe1ef96bd12947e6

RESEARCH PRODUCT

On the mechanistic behavior of highly efficient palladium-tetraphosphine catalytic systems for cross-coupling reactions: first spectroscopic and electrochemical studies of oxidative addition on Pd(0)/multidentate ferrocenylpolyphosphine complexes

Jean-cyrille Hierso David Evrard Dominique Lucas Philippe Meunier Yves Mugnier

subject

crystal structure Denticity redox reaction oxidative addition tetraphosphine chemistry.chemical_element mechanism 010402 general chemistry Electrochemistry Photochemistry 01 natural sciences Coupling reaction Catalysis Inorganic Chemistry [ CHIM.CATA ] Chemical Sciences/Catalysis cross-coupling reactions ferrocenylpolyphosphine complexes Physical and Theoretical Chemistry ComputingMilieux_MISCELLANEOUS electrochemical studies 010405 organic chemistry Chemistry Organic Chemistry [CHIM.CATA]Chemical Sciences/Catalysis palladium Combinatorial chemistry Oxidative addition 0104 chemical sciences 3. Good health catalytic systems reaction kinetics 31p nmr spectroscopy Palladium

description

Electrochemical studies carried out in conjunction with 31P NMR spectroscopy on the palladium(II)/palladium(0) halogeno complexes of the tetraphosphine 1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di...

year	journal	country	edition	language
2008-05-07

https://hal.archives-ouvertes.fr/hal-00460879

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