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RESEARCH PRODUCT
Di- and Tri-organotin(IV) Complexes ofN-Acetyltriglycine andN-Benzoyltriglycine: Synthesis and Spectroscopic Characterization
Michael VornefeldFriedo HuberGiuseppe RuisiMaria Teresa Lo Giudicesubject
DenticityLigandStereochemistrychemistry.chemical_elementGeneral ChemistryChemical synthesisMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundchemistryAmideHydroxideCarboxylateMethanolTindescription
Di- and tri-organotin(IV) derivatives of N-acetyltriglycine and N-benzoyltriglycine (HA) were obtained by refluxing equimolar mixtures of the ligand and the organotin(IV) oxide or hydroxide in methanol or acetone. According to the spectroscopic data, triorganotin(IV) derivatives adopt a trigonal-bipyramidal structure in which the planar R 3 Sn IV unit is bonded by a monodentate carboxylate group and a donor group, presumably the amide C=O. The reaction of HA with the appropriate diorganotin(IV) compounds gave both dicarboxylates R 2 SnA 2 , with six-coordinated tin, and dimeric tetra-organodistannoxanes {[R 2 SnA] 2 O}2, in which the tin atoms are essentially five-coordinated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1996-12-01 | Applied Organometallic Chemistry |