When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

6533b82ffe1ef96bd1295a09

RESEARCH PRODUCT

When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Eduards Bakis Andris Zicmanis Elina Priede

subject

chemistry.chemical_classification chemistry.chemical_compound Direct route chemistry Organic Chemistry Ionic liquid Organic chemistry Counterion Phosphate Metathesis Ion Trimethyl phosphate

description

Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.

year	journal	country	edition	language
2014-09-09	Synlett

https://doi.org/10.1055/s-0034-1379018

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