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RESEARCH PRODUCT

Oxidomolybdenum(VI) complexes with aminoalcohol bis(phenolate) [O,N,O,O′] ligands: Synthesis and catalytic studies

Reijo SillanpääAri LehtonenJuuso O. Hakala

subject

Inorganic Chemistrychemistry.chemical_compoundchemistryMolybdenumPolymer chemistryMaterials Chemistrychemistry.chemical_elementPhenolPhysical and Theoretical Chemistryta116CatalysisMethyl sulphide

description

Abstract Oxidomolybdenum(VI) complex [MoOCl(Ln)] with a tetradentate O3N-type aminoalcohol bis(phenol) was prepared as two separable isomers. These complexes can catalyse the epoxidation of cis-cyclooctene and sulphoxidation of tolyl methyl sulphide as well as the oxotransfer reaction between PPh3 and DMSO.

10.1016/j.inoche.2012.03.043http://juuli.fi/Record/0247501812