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RESEARCH PRODUCT
Quantum Dynamics of the 17O + 32O2 Collision Process
Grégoire GuillonGrégoire GuillonPascal HonvaultPascal Honvaultsubject
010304 chemical physicsIsotopeChemistryQuantum dynamics010402 general chemistryCollision01 natural sciences0104 chemical sciencesConnection (mathematics)Reaction rate constantAtmospheric chemistry0103 physical sciencesScattering theoryPhysical and Theoretical ChemistryAtomic physicsQuantumdescription
We report full quantum integral and differential cross sections and rate constants for the 17O + 32O2 reactive process. This constitutes the first quantum scattering study of the 17O16O16O system. We emphasize the comparison with the 18O + 32O2 collision in close connection to the mass-independent fractionation (hereafter referred to as MIF) puzzle for ozone in atmospheric chemistry. We find similar general trends in the cross sections and rate constants for both rare isotopes, but we note some singular behaviors peculiar to the use of 17O isotope, particularly at the lowest collision energies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-10-13 | The Journal of Physical Chemistry A |