6533b830fe1ef96bd12971bc

RESEARCH PRODUCT

Single ion magnet behaviour in a two-dimensional network of dicyanamide-bridged cobalt(II) ions

Barbara MachuraTomasz KlemensFrancesc LloretJulia VallejoJoanna Palion-gazdaMiguel Julve

subject

Single ionCoordination polymerInorganic chemistrychemistry.chemical_elementMagnetic susceptibilityIonInorganic Chemistrychemistry.chemical_compoundchemistryMagnetPhysical chemistrySingle ion magnetX-ray structureCobaltDicyanamide

description

A novel two-dimensional coordination polymer of the formula [Co(dca)2(atz)2]n (1) resulted from assembling trans-bis(2-amino-1,3,5-triazine)cobalt(II) motifs by dicyanamide spacers. Variable-temperature dc and ac magnetic susceptibility measurements of 1 show that the high-spin cobalt(II) ions act as single ion magnets (SIMs).

10.1039/c4dt03574ghttp://hdl.handle.net/20.500.12128/12587