6533b830fe1ef96bd129729a
RESEARCH PRODUCT
Disordered sodium alkoxides from powder data: crystal structures of sodium ethoxide, propoxide, butoxide and pentoxide, and some of their solvates
Martin U. SchmidtMaurice BeskeMaurice BeskeStephanie CronjeLukas Tapmeyersubject
Recrystallization (geology)Sodiumchemistry.chemical_elementAlcoholCrystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural scienceschemistry.chemical_compoundsolvateBärnighausen treeMaterials Chemistryddc:530Alkylchemistry.chemical_classificationSodium ethoxideChemistryMetals and AlloysResearch PapersAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic MaterialsisopropanolCrystallographysodium alkoxide548PXRDddc:540Alkoxidepowder dataPowder diffractiondescription
The crystal structures of NaOEt, NaOPr, NaOBu and NaOAm (Am = amyl = pentyl) were determined from powder data. These compounds crystallize in an anti-PbO structure in the space groups P 21 m and P4/nmm. Additionally, solvates with the composition NaOEt·2EtOH, NaOPr·2PrOH, NaOiPr·5iPrOH and NaOtAm·tAmOH were synthesized, and their structures were determined from single crystals. They form interesting chain structures of different compositions and topologies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-01-25 |