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RESEARCH PRODUCT
Do Extremely Bent Allenes Exist?
Mikko M. HänninenAnssi PeuronenHeikki M. Tuononensubject
bent allenesChemistryComputational chemistryOrganic ChemistryBent molecular geometryGeneral ChemistryElectronic structurePhysics::Chemical Physicstaipuneet alleenitelectronic structureCatalysiselektronirakennedescription
Bent allenes: Theoretical calculations show that extremely bent allenes, cyclic or acyclic, adopt a ground state that only bears a formal relationship to classical allenes. Consequently, five-membered ring allenes favor a carbene-like electronic structure and formally contain a trivalent carbon(II) center. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-06-25 | Chemistry - A European Journal |