Novel Hexanuclear Copper(II) Complex Built from a Simple Tetrachelating Triazole Ligand: Synthesis, Structure, and Magnetism

6533b831fe1ef96bd1298ea9

RESEARCH PRODUCT

Novel Hexanuclear Copper(II) Complex Built from a Simple Tetrachelating Triazole Ligand: Synthesis, Structure, and Magnetism

Sacramento Ferrer N. Ovèjak Javier Hernández-gil Francesc Lloret Alfonso Castiñeiras

subject

Models Molecular chemistry.chemical_classification Molecular Structure Stereochemistry Ligand Magnetism Magnetic Phenomena Temperature Triazole Salt (chemistry)chemistry.chemical_element Triazoles Ligands Copper Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Organometallic Compounds Physical and Theoretical Chemistry Copper

description

A new easy symmetric 3,5-disubstituted 1,2,4-triazole ligand (H3diV) by reaction with an excess of copper(II) salt has afforded a novel hexanuclear compound (Cu/HdiV ratio of 6:2) through a bis(trans-cis-cis-trans) binding mode, exhibiting two types of Cu(II) centers and two clearly distinguishable antiferromagnetic J1 (-234 cm(-1)) and J2 (-35 cm(-1)) coupling constants.

year	journal	country	edition	language
2013-02-20	Inorganic Chemistry

https://doi.org/10.1021/ic3027946

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