6533b831fe1ef96bd129913f
RESEARCH PRODUCT
Approaches to the preparation of carborane-containing carbosilane compounds.
F. TeixidorRosario NúñezRaikko KivekäsArántzazu GonzálezReijo SillanpääC. Viñassubject
chemistry.chemical_compoundchemistryHydrosilylationOrganic ChemistryCarboranechemistry.chemical_elementLithiumCrystal structurePhysical and Theoretical ChemistryBiochemistryCombinatorial chemistrydescription
[Structure: see text] A novel type of carborane cluster assembly has been successfully prepared using carbosilane derivatives as a scaffold. Two synthetic routes have been used: One involves the reaction of a carbosilane containing terminal Si-Cl functions with the lithium salt of the phenyl-o-carborane, and the second one consists of a highly efficient hydrosilylation of tetravinylsilane with the corresponding carboranylsilane. The crystal structure of this carborane-containing carbosilane compound has been determined by X-ray diffraction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-01-14 | Organic letters |