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RESEARCH PRODUCT
Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets
Thais GranchaJorge PasánJoan CanoFrancesc LloretCatalina Ruiz‐pérezEmilio PardoMiguel JulveYves JournauxJesús Ferrando-soriasubject
Steric effectschemistry.chemical_classificationBridging (networking)Mixed metalChemistryLigandStereochemistryMetals and AlloysGeneral ChemistryOpen frameworkCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyMagnetMaterials ChemistryCeramics and CompositesAlkylCurse of dimensionalitydescription
Increasing dimensionality [from 2D (1) to 3D (2)] and T(C) [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic Mn(II)(2)Cu(II)(3) open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.
year | journal | country | edition | language |
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2012-03-02 | Chemical Communications |