6533b831fe1ef96bd129983e

RESEARCH PRODUCT

Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

Thais GranchaJorge PasánJoan CanoFrancesc LloretCatalina Ruiz‐pérezEmilio PardoMiguel JulveYves JournauxJesús Ferrando-soria

subject

Steric effectschemistry.chemical_classificationBridging (networking)Mixed metalChemistryLigandStereochemistryMetals and AlloysGeneral ChemistryOpen frameworkCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyMagnetMaterials ChemistryCeramics and CompositesAlkylCurse of dimensionality

description

Increasing dimensionality [from 2D (1) to 3D (2)] and T(C) [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic Mn(II)(2)Cu(II)(3) open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.

https://doi.org/10.1039/c2cc17767f