The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

6533b831fe1ef96bd1299943

RESEARCH PRODUCT

The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

Julio Lloret-fillol Ignacio Rosa-pardo Luciana C. Schmidt Julia Pérez-prieto Miguel Claros Raquel E. Galian Carla Casadevall

subject

chemistry.chemical_classification PEROVSKITE CsPbBr3 Ligand Chemistry Metals and Alloys Reinforced carbon–carbon Nanoparticle Electron donor General Chemistry Photochemistry Catalysis Coupling reaction Surfaces Coatings and Films Electronic Optical and Magnetic Materials Catalysis //purl.org/becyt/ford/1 [https]chemistry.chemical_compound CARBON-CARBON COUPLING //purl.org/becyt/ford/1.4 [https]Materials Chemistry Ceramics and Composites PHOTOREDOX Alkyl Visible spectrum

description

We demonstrate here the suitability of CsPbBr3nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and an electron donor, thanks to the cooperative action between the nanoparticle surface and organic capping. Fil: Rosa-Pardo, Ignacio. Instituto de Ciencia Molecular; España. Universidad de Valencia; España Fil: Casadevall, Carla. Barcelona Institute Of Science And Technology. Institut Català D'investigació Química.; España Fil: Schmidt, Luciana Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Castro Claros, José Miguel. Barcelona Institute Of Science And Technology. Institut Català D'investigació Química.; España Fil: Galian Baca, Raquel Eugenia. Instituto de Ciencia Molecular; España. Universidad de Valencia; España Fil: Lloret-Fillol, Julio. Barcelona Institute Of Science And Technology. Institut Català D'investigació Química.; España Fil: Pérez-Prieto, Julia. Instituto de Ciencia Molecular; España. Universidad de Valencia; España

year	journal	country	edition	language
2020-05-01	Chemical Communications

https://doi.org/10.1039/d0cc01339k

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