6533b831fe1ef96bd1299a0b
RESEARCH PRODUCT
A fluorinated 2D magnetic coordination polymer
Iñigo J. Vitorica-yrezabalJavier López-cabrellesPablo J. BereciartuaGuillermo Mínguez EspallargasEugenio CoronadoSamuel Mañas‐valerosubject
chemistry.chemical_classificationMaterials scienceCoordination polymerNanotechnologyExfoliation jointCoordination complexInorganic Chemistrychemistry.chemical_compoundchemistryMagnetSurface modificationCompostos de coordinacióMolecular materialsLinkerMaterialsOpen airdescription
Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(ii) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-11-05 |