6533b832fe1ef96bd129a1ca

RESEARCH PRODUCT

Detection of the liquid ? liquid demixing by differential scanning calorimetry

Bernhard A. WolfEugeniusz Maderek

subject

chemistry.chemical_classificationMaterials scienceChromatographyPolymers and PlasticsAnalytical chemistryGeneral ChemistryPolymerCondensed Matter PhysicsDifferential scanning calorimetrychemistryMaterials ChemistryLiquid liquidChemical solutionPhase diagram

description

From theoretical considerations it is concluded that the demixing temperatures of moderately concentrated polymer solutions should manifest themselves in a change of the slope of the corresponding DSC trace; the effects are expected to suffice for detection by means of the commercially available dual furnace instrument DSC-2C from Perkin-Elmer.

https://doi.org/10.1007/bf00262190