Electrocatalytic Properties of Carbosilane‐Based Hyperbranched Polymers Functionalized with Interacting Ferrocenyl Units

6533b832fe1ef96bd129a1e7

RESEARCH PRODUCT

Electrocatalytic Properties of Carbosilane‐Based Hyperbranched Polymers Functionalized with Interacting Ferrocenyl Units

Gonzalo De La Cruz José Losada M. Pilar García-armada Beatriz Alonso Holger Frey Carmen M. Casado Hanna Schüle

subject

chemistry.chemical_classification Hydrosilylation Inorganic chemistry chemistry.chemical_element Polymer Electrocatalyst Electrochemistry Redox Inorganic Chemistry chemistry.chemical_compound chemistry Electrode Polymer chemistry Hydrogen peroxide Platinum

description

Two types of hyperbranched ferrocene-containing polycarbosilanes were obtained by hydrosilylation of polydiallylmethylsilane (hb-PDAMS) and polymethyldiundecenylsilane (hb-PMDUS) with diferrocenylmethylsilane. The redox properties of both polymers have been investigated both in solution and confined onto platinum electrodes. The electrocatalytic activity of polymer-modified electrodes toward the reduction of oxygen as well as the electrochemical reduction and oxidation of hydrogen peroxide has been examined.

year	journal	country	edition	language
2012-11-15	European Journal of Inorganic Chemistry

https://doi.org/10.1002/ejic.201201018

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