ChemInform Abstract: Enediolates and Dienediolates of Carboxylic Acids in Synthesis. Synthesis of β,γ-Epoxyacids from α-Chloroketones.

6533b832fe1ef96bd129ac33

RESEARCH PRODUCT

ChemInform Abstract: Enediolates and Dienediolates of Carboxylic Acids in Synthesis. Synthesis of β,γ-Epoxyacids from α-Chloroketones.

Félix Villar Ramon Mestres Eva M. Brun Salvador Gil Margarita Parra

subject

Allylic rearrangement chemistry chemistry.chemical_element Lithium General Medicine Combinatorial chemistry

description

Abstract Lithium dienolates of saturated or α,β-unsaturated acids react with α-chloroketones provide a convenient method for preparation of highly sustituted β,γ-epoxyacids. These highly reactive compounds lead in most cases to variable ammounts of the corresponding β-lactones and allylic alcohols.

year	journal	country	edition	language
2010-06-22	ChemInform

https://doi.org/10.1002/chin.199822081

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