6533b832fe1ef96bd129ad31
RESEARCH PRODUCT
Effect of the precursor's stoichiometry on the optoelectronic properties of methylammonium lead bromide perovskites
Michele SessoloAlan WongHenk J. BolinkGiulia Longosubject
Materials scienceBand gapBiophysicsNanoparticleHalide02 engineering and technologyElectroluminescence010402 general chemistry01 natural sciencesBiochemistrylaw.inventionlawThin filmbusiness.industryGeneral ChemistrySemiconductor device[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Optics0104 chemical sciencesOptoelectronics0210 nano-technologybusinessStoichiometryLight-emitting diodedescription
International audience; Methylammonium lead bromide (MAPbBr 3) perovskites have been widely studied in applications such as lasers and light-emitting diodes, thanks to their favorable bandgap, efficient charge transport, and the possibility of processing by simple solution methods. The film morphology has a large impact on the optical and electronic properties of the material; hence the deposition methods and the type of precursors used are crucial in the preparation of efficient optoelectronic devices. Here we studied the effect of the precursor´s stoichiometry of solution processed MAPbBr 3 thin films on their optical and electronic properties. We found a drastic effect of the stoichiometry on the resulting thin film morphology, and suggest the use of excess MA cations to enhance the photo-and electroluminescence of hybrid perovskites.
year | journal | country | edition | language |
---|---|---|---|---|
2017-03-23 |