6533b832fe1ef96bd129ae9f

RESEARCH PRODUCT

Versatile Electrochemical C-H Amination via Zincke Intermediates.

Siegfried R. WaldvogelSabine Möhle

subject

Green chemistryChemistryCationic polymerizationGeneral ChemistryElectrochemical TechniquesElectrochemistryCarbonCatalysischemistry.chemical_compoundPyridineOrganic chemistryOxidative coupling of methaneNitrogen sourceOxidation-ReductionAminationCopperAminationHydrogen

description

Simply by applying electricity, the amination reaction of a broad variety of arenes, heteroarenes, and benzylic substrates is achieved. Pyridine serves as the nitrogen source and the intermediate cationic species are well-protected from over-oxidation.

10.1002/anie.201502638https://pubmed.ncbi.nlm.nih.gov/25967883