6533b832fe1ef96bd129aea2

RESEARCH PRODUCT

Comparison of hard vaporization and soft ionization techniques in the mass spectrometry of some palladium(II) and platinum(II) complexes with C-bonded heterocyclic ligands

Bruno CrocianiRoberta SeragliaRoberta BertaniRiccardo PolloniPietro TraldiW. Cecchetto

subject

ChemistryInorganic chemistrychemistry.chemical_elementFast atom bombardmentMass spectrometryMass spectrometricInorganic ChemistryIonizationVaporizationMaterials ChemistryPhysical chemistryPhysical and Theoretical ChemistryPlatinumElectron ionizationPalladium

description

Abstract Electron impact, fast atom bombardment and laser induced vaporization techniques are compared in the mass spectrometric behaviour of some palladium(II) and platinum(II) complexes with C-bonded heterocyclic ligands of the type trans -[MCl(R N )(PPh 3 ) 2 ] [M = Pd, R N = 2-pyridyl, 1 ; 2-pyrazyl, 2; 2-pyrimidyl, 3; M = Pt, R N = 2-pyridyl, 4 ].

https://doi.org/10.1016/s0020-1693(00)80279-0