6533b833fe1ef96bd129bfcf

RESEARCH PRODUCT

LIESST Effect in Fe(II) 1,2,4-Triazole Chains

Philipp GütlichFranz RenzYann Garcia

subject

Materials scienceSpin statesGeneral Engineering124-TriazoleLight irradiation02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryPhotomagnetism01 natural sciencesLIESST0104 chemical scienceschemistry.chemical_compoundNuclear magnetic resonancechemistryMössbauer spectroscopyGeneral Earth and Planetary Sciences0210 nano-technologyGeneral Environmental Science

description

One-dimensional Fe(II) chains with 1,2,4-triazole as bridging ligands present the LIESST effect; i.e. their spin state switched from low-spin to high-spin after light irradiation at low temperature. This account summarizes the findings in this area of photomagnetism where 57Fe Mossbauer spectroscopy was used as a primary detection tool of the LIESST effect.

https://doi.org/10.2174/1877944105666150910195707