6533b833fe1ef96bd129bfe3

RESEARCH PRODUCT

Electrical magnitudes in gravitational and centrifugal systems

Javier GarridoVicente CompañMaría Lindón López

subject

GravitationElectromotive forceChemistryGeneral Chemical EngineeringSedimentation equilibriumElectrical conductionElectrodeElectrochemistryThermodynamicsMechanicsElectrochemistryElectrochemical potentialIon

description

Abstract A new formulation to study the non-equilibrium processes in gravitational and centrifugal electrochemical systems is developed. The driving forces and the fluxes are measurable quantities. The electrical equilibrium and the pure electrical conduction are described in an evident, simple and exact manner. Theoretical expressions of the emf for several gravitational cells are shown. Some differences are observed with those given in the literature ( eg the terminals density does not appear). The electrochemical potential of ion species is the basic piece in this study.

https://doi.org/10.1016/0013-4686(93)87004-w