6533b833fe1ef96bd129c0cf
RESEARCH PRODUCT
Solvent-Independent Electrode Potentials of Solids Undergoing Insertion Electrochemical Reactions: Part III. Experimental Data for Prussian Blue Undergoing Electron Exchange Coupled to Cation Exchange
Noemí MontoyaAntonio Doménech-carbóFritz Scholzsubject
Prussian blueChemistryDiffusionInorganic chemistryElectrochemistryRedoxSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventchemistry.chemical_compoundGeneral EnergyStandard electrode potentialElectrodePhysical and Theoretical ChemistryVoltammetrydescription
Prussian blue-modified electrodes immersed in K+-containing solutions can be used to obtain a solvent-independent redox potential system. On the basis of theoretical modeling of diffusion processes occurring under the conditions of voltammetry of immobilized particles, voltammetric and chronoamperometric data can be combined to obtain solvent-independent electrode potentials for the K+-assisted one-electron reduction of Prussian blue to Berlin white. Data for water, MeOH, EtOH, MeCN, DMS, DMF, and NM are provided.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-11-30 | The Journal of Physical Chemistry C |