6533b833fe1ef96bd129c1b0

RESEARCH PRODUCT

(Z)-4-(2-Naphthylamino)pent-3-en-2-one

Abdelghani OudahmaneMohamed Anoir HarradCorrado RizzoliDaniel AvignantBrahim Boualy

subject

CrystallographyHydrogen bondMaximum deviationGeneral ChemistryDihedral angleCondensed Matter PhysicsRing (chemistry)BioinformaticsOrganic Paperschemistry.chemical_compoundCrystallographychemistryQD901-999General Materials ScienceNaphthalene

description

The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of 39.78 (3)° with the naphthalene ring system. An intramolecular N—H...O hydrogen bond is observed.

10.1107/s1600536811024494http://scripts.iucr.org/cgi-bin/paper?S1600536811024494