6533b833fe1ef96bd129c1cf

RESEARCH PRODUCT

On the regeneration of thermally regenerative ammonia batteries

Fabrizio VicariAdriana D'angeloAlessandro GaliaYohan KoukoAlessandro LoffrediOnofrio Scialdone

subject

Battery (electricity)Thermally regenerative ammonia battery TRAB TREC Regeneration Waste heat Ammonia–copper complexMaterials scienceWaste managementGeneral Chemical Engineering02 engineering and technologySettore ING-IND/27 - Chimica Industriale E Tecnologica010402 general chemistry021001 nanoscience & nanotechnology7. Clean energy01 natural sciences0104 chemical sciencesAmmoniachemistry.chemical_compoundchemistryWaste heatMaterials ChemistryElectrochemistry0210 nano-technologyRegeneration (ecology)

description

In the past few years, thermally regenerative ammonia battery (TRAB) has been proposed as an effective tool to recover waste heat at temperatures below 130 °C. Most of the literature available is devoted to the power production step, with less attention being given to the regeneration step (e.g. the removal of ammonia from the anolyte). In this paper, the TRAB is analyzed with particular attention to the regeneration step and to the study of various generation of energy-regeneration cycles. It was shown that approximately 90 °C is necessary for the regeneration step due to the fact that ammonia is present in the anolyte mainly as a complex. Various cycles were performed with success, demonstrating the efficacy of the proposed regeneration step.

10.1007/s10800-018-1240-0http://dx.doi.org/10.1007/s10800-018-1240-0