6533b833fe1ef96bd129c33c

RESEARCH PRODUCT

A new enneanuclear nickel(II) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior.

Dai-zheng LiaoShi-ping YanGong-feng XuXin QiaoJing-yuan XuHai-bin SongYves JournauxJoan Cano

subject

Models MolecularChemistryMetals and AlloysStructure (category theory)chemistry.chemical_elementGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyNickelTrigonal prismCoordination ComplexesNickelFace (geometry)Materials ChemistryCeramics and CompositesCluster (physics)MagnetsPyrazolesSingle-molecule magnet

description

An enneanuclear nickel(II) complex with a rectangular face-centered trigonal prism structure bridged by μ(2)-pyrazolate, μ(6)-CO(3)(2-) and μ(3)-OH(-) groups was synthesized. It displays cluster glass-like magnetic behavior assigned to the single molecule magnet properties of {Ni(9)} clusters and weak intercluster interaction.

yearjournalcountryeditionlanguage
2011-12-07Chemical communications (Cambridge, England)
10.1039/c1cc16243hhttps://pubmed.ncbi.nlm.nih.gov/22143156