6533b834fe1ef96bd129d4a5
RESEARCH PRODUCT
Kronenethersubstituierte 1,4-Distyrylbenzole und ihre Komplexierung mit Alkalipikraten
Dirk SchwöppeHerbert Meiersubject
chemistry.chemical_classificationchemistry.chemical_compoundchemistryOrganic chemistryAlkali metalMedicinal chemistryCrown CompoundsCrown etherDichloromethanedescription
Crown Ether Substituted 1,4-Distyrylbenzenes and their Complexation with Alkali Picrates The 1,4-distyrylbenzenes 8 and 9, which contain two crown ether units, each, were prepared by Wittig—Horner reactions. Their complexation tendencies with alkali picrates (Li—Cs) in water/dichloromethane were investigated. Potas sium ions give the strongest complexes. Generally monomo-lecular 1:1-complexes are formed; however, [K-8] + [Pik]—, [K-9]+ [Pik]— and [Rb-8] + [Pik]— generate aggregates, for which a stairway structure is proposed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-06-01 | Journal für praktische Chemie |