6533b834fe1ef96bd129d68d

RESEARCH PRODUCT

Aurophilicity as a cofactor in crystal engineering. Dicyanoaurate(I) anion as a building block in a novel Co(II)–Au(I) bimetallic assembly

Enrique ColacioJosé Suárez-varelaJosé RuizRaikko KivekäsFrancesc LloretMarkku R. Sundberg

subject

AurophilicityStereochemistryCoordination polymerZeolite-like propertiesUNESCO::QUÍMICACrystal engineering010402 general chemistryCrystal engineering01 natural sciencesAurophilicity:QUÍMICA [UNESCO]CatalysisCofactorIonchemistry.chemical_compoundMaterials ChemistryBimetallic stripAurophilicity ; Crystal engineering ; Bimetallic ; Zeolite-like propertiesBimetallicbiologyUNESCO::QUÍMICA::Química inorgánica010405 organic chemistryChemistryMetals and AlloysGeneral ChemistryBlock (periodic table):QUÍMICA::Química inorgánica [UNESCO]3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyCeramics and Compositesbiology.protein

description

A 2D grid-shaped cyanide-bridged Co(II)–Au(I) bimetallic coordination polymer, [Co(DMF)2{Au(CN)2}2], has been prepared from the [Au(CN)2]2 building block; sheets associate pair-wise by aurophilic interactions and the compound exhibits zeolite-like properties. Lloret Pastor, Francisco, Francisco.Lloret@uv.es

yearjournalcountryeditionlanguage
2002-01-01
http://hdl.handle.net/10550/16687