6533b834fe1ef96bd129df0a
RESEARCH PRODUCT
N-Methyl-3-methylsulfonyl-N-nitroaniline
Zdzisław DaszkiewiczJacek ZaleskiBartosz Zarychtasubject
ChemistryHydrogen bondStereochemistrySubstituentGeneral ChemistryDihedral angleCondensed Matter PhysicsRing (chemistry)Medicinal chemistryBond lengthDelocalized electronchemistry.chemical_compoundAnilineNitroGeneral Materials Sciencedescription
In the title compound, C8H10N2O4S, the N—N bond length [1.3488 (18) A] indicates some double-bond character, while the torsion angle between the aromatic ring and the nitramine group [66.3 (2)°] rules out further delocalization in the molecule. The geometry of the methylsulfonyl substituent is quasi-tetrahedral, as expected. The crystal packing is stabilized by C—H⋯O hydrogen bonds, with the molecules arranged in chains extended along the [101] direction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-05-28 | Acta Crystallographica Section E Structure Reports Online |