6533b835fe1ef96bd129e9fb

RESEARCH PRODUCT

Dopamine interaction with a polyamine cryptand of 1H-pyrazole in the absence and in the presence of Cu(ii) ions. Crystal structure of [Cu2(H−1L](ClO4)3·2H2O

Enrique García-españaPilar NavarroJulio LatorreCarlos MirandaJose Antonio RamirezLaurent LamarqueFrancisco Escartí

subject

ChemistryCryptandMetals and AlloysGeneral ChemistryCrystal structurePyrazoleCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographychemistry.chemical_compoundDopamineMaterials ChemistryCeramics and CompositesmedicineTernary operationPolyaminemedicine.drug

description

The crystal structure of the binuclear Cu2+ complex [Cu2(H−1L)](ClO4)3 ·2H2O of the cryptand L = 1,4,7,8,11,14,17,20,21,24,29,32,33,36-tetradecaazapentacyclo[12.12.12.1 6,9.119,22,1,31,34]hentetraconta-6,9(41), 19(40), 21,31,34(39)-hexaene is presented; evidence for the formation in solution of binary L–dopamine and ternary Cu2+–L–dopamine complexes is presented.

https://doi.org/10.1039/b003231j