6533b835fe1ef96bd129eccb

RESEARCH PRODUCT

C–S bond cleavage by cobalt: synthesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C–S bond cleaved fragments

Pauli SaarenketoGudneppanavar RajsekharErkki KolehmainenKari RissanenChebrolu P. Rao

subject

ChemistryStereochemistryActivationchemistry.chemical_elementCrystal structureCharacterization (materials science)Inorganic ChemistrySynthesisProduct (mathematics)Polymer chemistryCrystal StructureMaterials ChemistrySaltsPhysical and Theoretical ChemistryOxidative cleavageCobaltBond cleavage

description

1,2-Di-(o-salicylaldiminophenylthio)ethane reacts with Co(II) salts to form a complex with oxidative cleavage of the C–S bond, to result in the formation of a Co(III) complex of the cleaved ligands.

https://doi.org/10.1016/s1387-7003(02)00522-1