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RESEARCH PRODUCT
Synthesis of Chlorinated Biphenyls by Suzuki Cross-Coupling Using Diamine or Diimine-Palladium Complexes
Noora KuulojaRobert FranzénKari RissanenYoujun XuTuula Kylmäläsubject
chemistry.chemical_compoundchemistrySuzuki reactionDiamineOrganic ChemistryPolymer chemistryOrganic chemistrychemistry.chemical_elementMethanolPhysical and Theoretical ChemistryDiimineChlorinated BiphenylsPalladiumdescription
Several novel diimines (Salen-type ligands) 2a–2i and their reduced diamine counterparts 3b,3d–3g and 3i form complexes 4a–4i, 5b,5d–5g, and 5i with PdCl2 in DMF or methanol. Using 1 mol-% of the isolated complexes 4e and 5f many polychlorinated biphenyls (PCBs) can be prepared in moderate to excellent yields according to the Suzuki crosscoupling protocol with contact to air. Several 4-acetylbiphen
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-08-01 | European Journal of Organic Chemistry |