6533b835fe1ef96bd129fedc

RESEARCH PRODUCT

Graphical representation of polynuclear acid-base and complex equilibria.

G.ramis RamosM.c.garcía Alvarez-coqueC.mongay Fernández

subject

ChemistryPhase (matter)Resolution (electron density)ThermodynamicsBinary numberRepresentation (mathematics)Base (topology)Analytical Chemistry

description

Abstract A calculation procedure for diagrams of log CM = ƒ(pL) at various values of the ratio of analytical concentrations, CL/CM, in polynuclear binary systems is described. The diagrams are useful in the resolution of analytical problems of practical interest involving acid-base equilibria (such as the preparation of buffer solutions) and complex equilibria. The presence of a solid phase is also considered.

10.1016/0039-9140(83)80177-5https://pubmed.ncbi.nlm.nih.gov/18963464